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- W2023530782 abstract "The structure of [Ru3(CO)10(μ1-η2-c-dpp) = cis-1,2-bis(diphenylphosphino)ethene) has been determined by X-ray crystallography. The crystals are monoclinic, space group P21/n, with cell dimensions: a = 10.4590(17), b = 24.197(6), c = 14.500(4) Å, β = 100.003 (22)° and Z = 4. This structure was refined to give R = 0.031 and Rw = 0.028 using 5052 reflections with I > 2σ-(I) in the range of 2 ≤ 2θ ≤ 50° (Mo Kα). The structure suggested previously to contain a 1,2-bridging c-dpp ligand is now found to contain the ligand in a 1,1-chelating geometry, which is also maintained in solution as indicated by the large downfield 31P coordination shift. This five-membered chelate ring is not perpendicular as observed for a similar ring in [Ru3(CO)10(μ1-η2-bipy)] (bipy = 2,2′-bipyridine) but nearly coplanar with the Ru3 plane. The synthesis and the structures of [M3(CO)10,(LL)] and [M2(CO)6(LL)] (M Fe, Ru or Os; LL = chelating c-dpp or bridging 1,2-bis(dimethylarsino)tetrafluorocyclobutene) are compared and a general reaction mechanism from [M3(CO)12] to [M3(CO)10(LL)] and [M2(CO)6(LL)] is proposed." @default.
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- W2023530782 date "1993-06-01" @default.
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- W2023530782 title "Structural characterization of[Ru3(CO)10{μ1-gh2-cis-1,2-bis (diphenylphosphino)ethene}]" @default.
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- W2023530782 doi "https://doi.org/10.1016/0022-328x(93)80338-c" @default.
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