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- W2023531906 abstract "The new pseudo-binary intermetallic compound, Ti11(Sb,Sn)8, has been synthesized by reacting Ti and Sb in a Sn flux at 1100°C and its structure determined from both single-crystal X-ray and neutron diffraction data (orthorhombic, Pnma, Z=4, X-ray diffraction at 90 K: a=14.6877(6) Å, b=5.5677(2) Å, c=17.7207(7) Å, V=1449.14(10) Å3, neutron diffraction at room temperature: a=14.677(6) Å, b=5.577(3) Å, c=17.716 (6) Å, V=1450(1) Å3). The structure contains two differently oriented repeating layers and interstitial atoms that are closely connected to make linear chains aligned along the crystal b axis. The compound exhibits mixed site occupancies of Sb and Sn on the anion sites. The phase width (Sb/Sn ratio=0.98–1.40) was determined by microprobe elemental analysis. The electrical resistivity of a single crystal as a function of temperature is anisotropic (ρ//b=1∼2×10−1 mΩ·cm, ρ⊥b=0.5×10−1 mΩ·cm) and confirms that this compound is metallic. Magnetic susceptibility measurements show Pauli paramagnetism." @default.
- W2023531906 created "2016-06-24" @default.
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- W2023531906 date "2001-02-01" @default.
- W2023531906 modified "2023-10-14" @default.
- W2023531906 title "Structure and Physical Properties of the New Pseudo-binary Intermetallic Compound Ti11(Sb,Sn)8" @default.
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- W2023531906 doi "https://doi.org/10.1006/jssc.2000.9080" @default.
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