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• W2023532514 abstract "The kinetics of CO 2 electroadsorption on electrodispersed Pt electrodes have been investigated in different acid electrolytes. The kinetic data obtained at different adsorption potentials, adsorption times and CO 2 concentrations in solution have been interpreted in terms of two complex reaction mechanisms involving the formation of strongly and weakly bound reduced CO 2 adsorbates through reactions involving s-H and w-H adatoms, respectively, and carbon dioxide. The reaction mechanism between H adatoms and CO 2 implies the initial electroadsorption of H atoms, the transport of CO 2 from the bulk of the solution to the reaction interface, and the formation of the reduced CO 2 adsorbate. Under certain conditions, particularly when s-H adatoms are involved, the entire reaction approaches mass transport rate control. Conversely, the reaction between w-H adatoms and CO 2 appears as a rather slow process." @default.
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• W2023532514 date "1990-03-01" @default.
• W2023532514 modified "2023-09-27" @default.
• W2023532514 title "Kinetics of CO2 electroadsorption on electrodispersed platinum electrodes in acid solutions" @default.
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• W2023532514 doi "https://doi.org/10.1016/0022-0728(90)87044-k" @default.
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