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- W2023552205 abstract "Aqueous hydrogen peroxide thermally decomposes into two hydroxyl radicals which readily initiate a radical polymerization process. Ethylenic monomers and aqueous hydrogen peroxide are generally nonmiscible liquids in all proportions, and the addition of an alcohol to the reaction medium greatly modifies the thermodynamic conditions. Liquid and solid products are obtained having 1.7 to 1.9 hydroxyl groups per macromolecule and their average molecular weights vary between 700 to 100,000. For diene monomer polymerization, low molecular weight oligomers as well as higher molecular weight polymers are obtained. Structures of the diene polymers obtained show that aqueous hydrogen peroxide-initiated polymerization proceeds by a 1, 2 addition for their initiation step and a 1, 4 addition for propagation." @default.
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- W2023552205 date "2007-03-08" @default.
- W2023552205 modified "2023-10-16" @default.
- W2023552205 title "Radical initiated synthesis of hydroxyl terminated polymers using aqueous hydrogen peroxide as initiator" @default.
- W2023552205 cites W2127365925 @default.
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- W2023552205 doi "https://doi.org/10.1002/polc.5070420104" @default.
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