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- W2023554720 abstract "The initiation step in radical polymerization of Si-containing vinyl monomers with arylthiyl radicals (ArS.) has been studied by the flash photolysis method. Rate constants for reversible addition reactions of ArS. with various Si-containing vinyl monomers have been determined by the selective radical scavenging method. For each thiyl radical, the reactivities for CH2CHX increased in the order:X=C(CH3)3(CH2)3CH2Si(OCH3)3⩽CH2Si(CH3)3∼Si(OCH3)3∼Si(CH3)3<<C6HSi(CH3)3−p∼C6H4Si(CH3)3−p The reactivity of the CC was increased by the substitution of the Si atom at vinyl and allyl positions. The polar and resonance factors of Si-containing monomers were evaluated from the kinetic data, which were compared with the Alfrey-PriceQ-e scheme obtained from the copolymerization data." @default.
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- W2023554720 date "1990-10-01" @default.
- W2023554720 modified "2023-10-16" @default.
- W2023554720 title "Flash photolysis study of initiation step in radical polymerization of Si-containing vinyl monomers: reactivities to arylthiyl radicals" @default.
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- W2023554720 doi "https://doi.org/10.1016/0032-3861(90)90028-w" @default.
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