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- W2023557450 abstract "Abstract A new bronze-type phase of composition (NH 4 ) 0.40±0.02 V 2 O 5 is obtained around 230°C during the thermal decomposition of NH 4 VO 3 in hydrogen atmosphere. The bronze intermediate is characterized by X-ray diffraction, electrical conductivity, magnetic susceptibility, and ESR studies. It is found to be isostructural with other known β-type vanadium bronzes of general formula M x V 2 O 5 , where M is usually a monovalent metal. Electrical conductivity and magnetic studies indicate the localized character of conduction electrons at V +4 sites. At high temperatures (>400°C), the bronze undergoes decomposition and subsequent reduction to V 2 O 3 in hydrogen atmosphere." @default.
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- W2023557450 date "1974-03-01" @default.
- W2023557450 modified "2023-10-16" @default.
- W2023557450 title "Preparation and studies of a new ammonium vanadium bronze, (NH4)xV2O5" @default.
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- W2023557450 doi "https://doi.org/10.1016/0022-4596(74)90085-1" @default.
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