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• W2023561057 endingPage "5837" @default.
• W2023561057 startingPage "5833" @default.
• W2023561057 abstract "Abstract The millimeter‐wave absorption and Fourier transform microwave spectra of five isotopologues of the 1:1 adduct of dimethoxymethane–water have been measured in supersonic expansions. Each rotational transition appears as a quintuplet, due to the internal rotation of the two methyl groups, which are nonequivalent in the adduct. The water moiety, linked asymmetrically to dimethoxymethane, behaves as a proton donor to one of its oxygen atoms and interferes with the internal rotation of the farther methyl group through a CH⋅⋅⋅O interaction. From the analysis of the observed splittings, the V 3 barriers to the internal rotation of the two methyl groups have been determined to be 6.83(8) and 6.19(8) kJ mol −1 . The hydrogen bond structural parameters have been determined, the OH⋅⋅⋅O and CH⋅⋅⋅O distances being 1.93(1) and 2.78(4) Å, respectively." @default.
• W2023561057 created "2016-06-24" @default.
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• W2023561057 date "2007-06-25" @default.
• W2023561057 modified "2023-10-17" @default.
• W2023561057 title "Noncovalent Interactions and Internal Dynamics in Dimethoxymethane–Water" @default.
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• W2023561057 doi "https://doi.org/10.1002/chem.200700076" @default.
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