Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023561535> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2023561535 abstract "Abstract The crystal structures of the title compounds have been determined from three-dimensional X-ray counter data. C 8 H 8 Te(CH 2 CHCH 2 )Br (I) is orthorhombic, space group Pbca with a 9.642(1), b 25.586(7), c 9.680(3) A, Z = 8. The structure has been refined to R 5.2% for 1262 observed reflections. C 8 H 8 Te(CH 2 COPh)Br (II) is orthorhombic, space group Pccn with a 23.593(6), b 14.337(3), c 9.180(2) A, Z = 8. R = 5.5% for 1374 reflections. C 8 H 8 Te(CD 3 )I (III) is orthorhombic, space group Pbca with a 11.200(3), b 15.976(2), c 23.328(3) A, Z = 16. R = 5.6% for 2142 reflections. In I and II, tellurium is coordinated in an approximately octahedral geometry by the organic residues and three halogen contacts, with TeC and TeBr distances in the ranges 2.14(1)–2.19(1) A and 3.328(2)–3.368(2) A in (I) and 2.12(1)–2.18(1) A and 3.292(2)–3.391(2) A in II. In III, each of the two crystallographically independent complexes has tellurium coordinated in a distorted octahedral geometry. The TeC bond lengths are 2.10(2)–2.16(2) A. In each case two TeI distances are in the range 3.596(2)–3.688(2) A and a third, longer interaction (3.870(2) and 4.112(2) A) completes the coordination. In each of the structures I–III the three covalent TeC bonds are oriented cis within the octahedra and exert a trans bond-lengthening effect on the Tehalogen interactions, precluding covalent-type bonding; the structures are essentially ionic, (C 8 H 8 TeR) + cations and halide anions forming extended arrays." @default.
- W2023561535 created "2016-06-24" @default.
- W2023561535 creator A5026215971 @default.
- W2023561535 creator A5027446018 @default.
- W2023561535 date "1982-08-01" @default.
- W2023561535 modified "2023-09-27" @default.
- W2023561535 title "The crystal structures of 1-allyl-1-bromo-3,4-benzo-1-telluracyclopentane [C8H8Te(C3H5)Br], 1-phenacyl-1-bromo-3,4-benzo-1-telluracyclopentane [C8H8Te(C8H7O)Br] and 1-deuteromethyl-1-iodo-3,4-benzo-1-telluracyclopentane [C8H8Te(CD3)I]; the trans effect in organotellurium bromides and iodides" @default.
- W2023561535 cites W1016811321 @default.
- W2023561535 cites W1963958682 @default.
- W2023561535 cites W1970551227 @default.
- W2023561535 cites W1993264916 @default.
- W2023561535 cites W2025623118 @default.
- W2023561535 cites W2030841140 @default.
- W2023561535 cites W2070365098 @default.
- W2023561535 cites W2073653983 @default.
- W2023561535 cites W2951228145 @default.
- W2023561535 cites W3137810903 @default.
- W2023561535 cites W3138417038 @default.
- W2023561535 doi "https://doi.org/10.1016/0022-328x(82)80005-3" @default.
- W2023561535 hasPublicationYear "1982" @default.
- W2023561535 type Work @default.
- W2023561535 sameAs 2023561535 @default.
- W2023561535 citedByCount "15" @default.
- W2023561535 countsByYear W20235615352013 @default.
- W2023561535 crossrefType "journal-article" @default.
- W2023561535 hasAuthorship W2023561535A5026215971 @default.
- W2023561535 hasAuthorship W2023561535A5027446018 @default.
- W2023561535 hasConcept C115624301 @default.
- W2023561535 hasConcept C155860418 @default.
- W2023561535 hasConcept C178790620 @default.
- W2023561535 hasConcept C179104552 @default.
- W2023561535 hasConcept C185592680 @default.
- W2023561535 hasConcept C193547582 @default.
- W2023561535 hasConcept C198819137 @default.
- W2023561535 hasConcept C2780263894 @default.
- W2023561535 hasConcept C2781311116 @default.
- W2023561535 hasConcept C32909587 @default.
- W2023561535 hasConcept C37243968 @default.
- W2023561535 hasConcept C39297587 @default.
- W2023561535 hasConcept C46062151 @default.
- W2023561535 hasConcept C538181303 @default.
- W2023561535 hasConcept C71240020 @default.
- W2023561535 hasConcept C8010536 @default.
- W2023561535 hasConceptScore W2023561535C115624301 @default.
- W2023561535 hasConceptScore W2023561535C155860418 @default.
- W2023561535 hasConceptScore W2023561535C178790620 @default.
- W2023561535 hasConceptScore W2023561535C179104552 @default.
- W2023561535 hasConceptScore W2023561535C185592680 @default.
- W2023561535 hasConceptScore W2023561535C193547582 @default.
- W2023561535 hasConceptScore W2023561535C198819137 @default.
- W2023561535 hasConceptScore W2023561535C2780263894 @default.
- W2023561535 hasConceptScore W2023561535C2781311116 @default.
- W2023561535 hasConceptScore W2023561535C32909587 @default.
- W2023561535 hasConceptScore W2023561535C37243968 @default.
- W2023561535 hasConceptScore W2023561535C39297587 @default.
- W2023561535 hasConceptScore W2023561535C46062151 @default.
- W2023561535 hasConceptScore W2023561535C538181303 @default.
- W2023561535 hasConceptScore W2023561535C71240020 @default.
- W2023561535 hasConceptScore W2023561535C8010536 @default.
- W2023561535 hasLocation W20235615351 @default.
- W2023561535 hasOpenAccess W2023561535 @default.
- W2023561535 hasPrimaryLocation W20235615351 @default.
- W2023561535 hasRelatedWork W1580735046 @default.
- W2023561535 hasRelatedWork W1981718565 @default.
- W2023561535 hasRelatedWork W1983888148 @default.
- W2023561535 hasRelatedWork W1983970239 @default.
- W2023561535 hasRelatedWork W1995560752 @default.
- W2023561535 hasRelatedWork W2009543419 @default.
- W2023561535 hasRelatedWork W2016200211 @default.
- W2023561535 hasRelatedWork W2020444269 @default.
- W2023561535 hasRelatedWork W2025623118 @default.
- W2023561535 hasRelatedWork W2035834095 @default.
- W2023561535 hasRelatedWork W2041453050 @default.
- W2023561535 hasRelatedWork W2044735092 @default.
- W2023561535 hasRelatedWork W2064695317 @default.
- W2023561535 hasRelatedWork W2072828865 @default.
- W2023561535 hasRelatedWork W2950363625 @default.
- W2023561535 hasRelatedWork W2952813578 @default.
- W2023561535 hasRelatedWork W627000267 @default.
- W2023561535 hasRelatedWork W782481732 @default.
- W2023561535 hasRelatedWork W814818941 @default.
- W2023561535 hasRelatedWork W2487889395 @default.
- W2023561535 isParatext "false" @default.
- W2023561535 isRetracted "false" @default.
- W2023561535 magId "2023561535" @default.
- W2023561535 workType "article" @default.