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- W2023561631 abstract "Oxidative degradation of aromatic pollutant 2,4,6-trichlorophenol to 2,6-dichloro-1,4-benzoquinone was found to be efficiently catalyzed by the iron(III) complex of tetrakis(3,5-disulfonatomesityl)porphyrin (FeTMPS) associated with KHSO5 as an oxygen atom donor [1–3]. The kinetics of this reaction was investigated at 20°C, pH 3 by determining the dependence of the reaction rate on factors such as concentration of 2,4,6-trichlorophenol, FeTMPS and KHSO5. For this reaction, the proposed mechanism involves the formation of 2,6-dichlorobenzoquinone via a peroxidase-type oxidation of the chlorinated phenol." @default.
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- W2023561631 date "1996-11-01" @default.
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- W2023561631 title "Kinetic investigations of oxidative degradation of aromatic pollutant 2,4,6-trichlorophenol by an iron-porphyrin complex, a model of ligninase" @default.
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- W2023561631 doi "https://doi.org/10.1016/s1381-1169(96)00105-7" @default.
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