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• W2023561680 abstract "Abstract Novel chemosensor, 1,1,2-trimethyl-1 H -benzo[ e ]indoline based thio-β-enaminone (TBE) was developed with excellent sensitivity and selectivity for Cu 2+ ions. In comparison with different cations (Na + , Mg 2+ , Al 3+ , K + , Ca 2+ , Mn 2+ , Co 2+ , Ni 2+ , Zn 2+ , Cd 2+ , Ba 2+ , La 3+ , Hg 2+ , Pb 2+ ), TBE gave pronounced 20-fold fluorescence enhancement for Cu 2+ ions, which remained unaffected in presence of other interfering metal ions. The ratiometric binding of TBE–Cu 2+ complex determined from Job's plot gave 1:1 interaction, which was confirmed by ESI-MS. Binding of Cu 2+ ions to TBE was studied over the wide pH range and the result demonstrated maximum fluorescence enhancement in the pH range of 3.0–10. The binding association constant ( K a ) value determined from Benesi–Hildebrand equation was 1.10 × 10 4  M −1 . The high detection limit in micromolar range (8.2 × 10 −7  M) for Cu 2+ ions makes TBE a suitable candidate for the development of a potential probe. Applicability of TBE to detect Cu 2+ ions in human serum and tap water has been demonstrated." @default.
• W2023561680 created "2016-06-24" @default.
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• W2023561680 date "2014-11-01" @default.
• W2023561680 modified "2023-10-03" @default.
• W2023561680 title "A highly selective fluorescent chemosensor based on thio-β-enaminone analog with a turn-on response for Cu(II) in aqueous media" @default.
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• W2023561680 doi "https://doi.org/10.1016/j.snb.2014.06.100" @default.
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