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- W2023562470 abstract "The reaction of the salts [Bu4N]2Re2X8, where X = Cl or Br, with 1,2-bis(diphenylphosphino)ethane, abbreviated dppe, affords the halogen-bridged dimers [ReX3(dppe)]2 which contain magnetically dilute rhenium(III) centers. The properties of these complexes are contrasted with those found for the related 2,5- dithiahexane complexes [ReX3(DTH)]2 in which the dominant structural feature is a strong rhenium-rhenium bond. The reaction of [Bu4N]2Re2Cl8 with 2,2′-bipyridyl in n-butanol leads to the formation of unreduced and reduced phases, whose stoichiometries approach [ReCl3 (bipy),3/2H2O]n and [ReCl2·5(bipy),3/8C4H9OH]n respectively, but which do not structurally resemble the analogous complexes with dppe or DTH." @default.
- W2023562470 created "2016-06-24" @default.
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- W2023562470 date "1975-01-01" @default.
- W2023562470 modified "2023-09-23" @default.
- W2023562470 title "Complex halides of the transition metals. Part XVI. the octahalodirhenate(III) anions. Reactions with the bidentate donors 1,2-bis(diphenylphosphino)ethane and 2,2′-bipyridyl" @default.
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- W2023562470 doi "https://doi.org/10.1016/s0020-1693(00)90172-5" @default.
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