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• W2023563516 abstract "The title complex, [Cu4(C12H22N4O4)(C10H8N2)4](ClO4)4, has a novel tetra­nuclear copper(II) cation with the oxamidate and ethanol­ate groups of a trans tetra­anion of N,N′-bis­[3-(hy­droxy­ethyl­amino)­propyl]oxamide (H4heap) as bridges. The Cu⋯Cu separation through the oxamide group is 5.1592 (15) Å, while those through the two ethanol­ate bridges are 3.3845 (13) and 3.3392 (13) Å. The two central copper(II) ions are in square-planar N2O2 environments, while the two terminal copper(II) ions have distorted N4O square-pyramidal geometries. The heap4− ligand, with an imino­alcohol form, has both an oxamide and two ethanol­ate bridges. Two of the four perchlorate anions are disordered and have long contacts with the square-planar CuII ions. The three-dimensional structure features arene–perchlorate C—H⋯O hydrogen bonds and π–π stacking." @default.
• W2023563516 created "2016-06-24" @default.
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• W2023563516 date "2010-07-08" @default.
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• W2023563516 title "Tetrakis(2,2′-bipyridine)-1κ⁴<i>N</i>,<i>N</i>′;4κ⁴<i>N</i>,<i>N</i>′-{μ₄-<i>N</i>,<i>N</i>′-bis[3-(2-oxidoethylamino)propyl]oxamidato(4−)-1:2:3:4κ<i>O</i>:κ³<i>N</i>,<i>N</i>′,<i>O</i>′:κ³<i>O</i>′′,<i>N</i>′′,<i>N</i>′′′:κ<i>O</i>′′′}tetracopper(II) tetrakis(perchlorate)" @default.
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• W2023563516 doi "https://doi.org/10.1107/s0108270110026089" @default.
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