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- W2023563810 abstract "We report on a Ni L$_{2,3}$ edges x-ray absorption spectroscopy (XAS) study in $R$NiO$_3$ perovskites. These compounds exhibit a metal to insulator ($MI$) transition as temperature decreases. The L$_{3}$ edge presents a clear splitting in the insulating state, associated to a less hybridized ground state. Using charge transfer multiplet calculations, we establish the importance of the crystal field and 3d spin-orbit coupling to create a mixed-spin ground state. We explain the $MI$ transition in $R$NiO$_3$ perovskites in terms of modifications in the Ni$^{3+}$ crystal field splitting that induces a spin transition from an essentially low-spin (LS) to a mixed-spin state." @default.
- W2023563810 created "2016-06-24" @default.
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- W2023563810 date "2005-01-26" @default.
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- W2023563810 title "Spin-orbit-induced mixed-spin ground state in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi>R</mml:mi><mml:mi mathvariant=normal>Ni</mml:mi><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>perovskites probed by x-ray absorption spectroscopy: Insight into the metal-to-insulator transition" @default.
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- W2023563810 doi "https://doi.org/10.1103/physrevb.71.020406" @default.
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