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- W2023563871 abstract "The conversion of [2-deutero-3-fluoro-D-Ala8]cyclosporin A (1) to a dehydroalanine analog [Δ-Ala8]cyclosporin A (2) was achieved with lithium diisopropylamide in THF at low temperature. This dehydro compound is a useful intermediate for the preparation of position 8 analogs of cyclosporin A formed from it by the conjugate addition of thiol compounds. NMR conformational studies have provided evidence for the restoration of D-stereochemistry in the modified Ala8 residues. The preparation of several of these cyclosporin analogs and their bioactivities are described." @default.
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- W2023563871 date "1992-01-01" @default.
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- W2023563871 title "Analogs of cyclosporin A modified at the D-Ala8 position." @default.
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- W2023563871 doi "https://doi.org/10.7164/antibiotics.45.94" @default.
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