Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023569861> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W2023569861 endingPage "842" @default.
- W2023569861 startingPage "832" @default.
- W2023569861 abstract "The reaction of nitrous acid with 4-alkyl- or 4-aryl-thiosemicarbazides, as well as the reaction of alkyl- or aryl-isothiocyanates with hydrazoic acid, leads to the identical 5-(substituted)amino-1,2,3,4-thiatriazole. This has been established by infrared absorption and chemical degradation studies. The reaction of the 5-(substituted)amino-1,2,3,4-thiatriazoles with aqueous bases leads to two competitive reactions: (1) degradation to an isothiocyanate and azide ion, and (2) isomerization to a 1-substituted-tetrazole-5-thiol, the extent of path (1) or (2) depending on the nature of the substituent. Path (1) predominates when the substituent is alkyl, whereas when the substituent is aryl both paths (1) and (2) occur, the relative proportion depending on the electrical nature of the aromatic group, path (2) increasing as the electronegativity increases. The 1-aryl-tetrazole-5-thiols were found to be thermally unstable at their melting points, degrading more or less violently to one mole proportion of pure nitrogen with the formation of sulphur and organic products of lower melting point as yet unidentified. Theories to account for these observations are presented and discussed." @default.
- W2023569861 created "2016-06-24" @default.
- W2023569861 creator A5013512151 @default.
- W2023569861 creator A5042631478 @default.
- W2023569861 creator A5054391673 @default.
- W2023569861 date "1957-08-01" @default.
- W2023569861 modified "2023-10-16" @default.
- W2023569861 title "THE REACTION OF NITROUS ACID WITH 4-SUBSTITUTED-THIOSEMICARBAZIDES" @default.
- W2023569861 doi "https://doi.org/10.1139/v57-116" @default.
- W2023569861 hasPublicationYear "1957" @default.
- W2023569861 type Work @default.
- W2023569861 sameAs 2023569861 @default.
- W2023569861 citedByCount "78" @default.
- W2023569861 countsByYear W20235698612012 @default.
- W2023569861 countsByYear W20235698612013 @default.
- W2023569861 countsByYear W20235698612014 @default.
- W2023569861 countsByYear W20235698612015 @default.
- W2023569861 countsByYear W20235698612016 @default.
- W2023569861 countsByYear W20235698612019 @default.
- W2023569861 countsByYear W20235698612020 @default.
- W2023569861 countsByYear W20235698612021 @default.
- W2023569861 crossrefType "journal-article" @default.
- W2023569861 hasAuthorship W2023569861A5013512151 @default.
- W2023569861 hasAuthorship W2023569861A5042631478 @default.
- W2023569861 hasAuthorship W2023569861A5054391673 @default.
- W2023569861 hasConcept C126661725 @default.
- W2023569861 hasConcept C155647269 @default.
- W2023569861 hasConcept C161790260 @default.
- W2023569861 hasConcept C178790620 @default.
- W2023569861 hasConcept C184651966 @default.
- W2023569861 hasConcept C185592680 @default.
- W2023569861 hasConcept C2776419827 @default.
- W2023569861 hasConcept C2778444112 @default.
- W2023569861 hasConcept C2778689049 @default.
- W2023569861 hasConcept C2779632193 @default.
- W2023569861 hasConcept C2780263894 @default.
- W2023569861 hasConcept C2780827033 @default.
- W2023569861 hasConcept C2780997848 @default.
- W2023569861 hasConcept C2781076698 @default.
- W2023569861 hasConcept C75473681 @default.
- W2023569861 hasConceptScore W2023569861C126661725 @default.
- W2023569861 hasConceptScore W2023569861C155647269 @default.
- W2023569861 hasConceptScore W2023569861C161790260 @default.
- W2023569861 hasConceptScore W2023569861C178790620 @default.
- W2023569861 hasConceptScore W2023569861C184651966 @default.
- W2023569861 hasConceptScore W2023569861C185592680 @default.
- W2023569861 hasConceptScore W2023569861C2776419827 @default.
- W2023569861 hasConceptScore W2023569861C2778444112 @default.
- W2023569861 hasConceptScore W2023569861C2778689049 @default.
- W2023569861 hasConceptScore W2023569861C2779632193 @default.
- W2023569861 hasConceptScore W2023569861C2780263894 @default.
- W2023569861 hasConceptScore W2023569861C2780827033 @default.
- W2023569861 hasConceptScore W2023569861C2780997848 @default.
- W2023569861 hasConceptScore W2023569861C2781076698 @default.
- W2023569861 hasConceptScore W2023569861C75473681 @default.
- W2023569861 hasIssue "8" @default.
- W2023569861 hasLocation W20235698611 @default.
- W2023569861 hasOpenAccess W2023569861 @default.
- W2023569861 hasPrimaryLocation W20235698611 @default.
- W2023569861 hasRelatedWork W1989648354 @default.
- W2023569861 hasRelatedWork W2010860799 @default.
- W2023569861 hasRelatedWork W2016256155 @default.
- W2023569861 hasRelatedWork W2032165875 @default.
- W2023569861 hasRelatedWork W2043456284 @default.
- W2023569861 hasRelatedWork W2060105492 @default.
- W2023569861 hasRelatedWork W2112529990 @default.
- W2023569861 hasRelatedWork W2126897705 @default.
- W2023569861 hasRelatedWork W2944958865 @default.
- W2023569861 hasRelatedWork W4200274514 @default.
- W2023569861 hasVolume "35" @default.
- W2023569861 isParatext "false" @default.
- W2023569861 isRetracted "false" @default.
- W2023569861 magId "2023569861" @default.
- W2023569861 workType "article" @default.