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- W2023571487 abstract "The microstructural changes associated with the lowering of hydrophilic/hydrophobic phase separation in the ionomer can reduce the molecular permeation without compensating the ionic conductivity significantly. Motivated by this idea, a hydrophilic polymer, poly(vinyl alcohol) (PVA) was selected as the polymer matrix of the proton exchange membranes and the protogenic sulfonic acid groups were introduced by chlorosulfonic acid through a condensation reaction. Glutaraldehyde was used as the cross-linking agent to improve both the mechanical and thermal stabilities of the membrane. The chemical structure and microstructural features of the membranes have been analyzed using FTIR-ATR and DSC, respectively. The different states of water in the membranes were analyzed and the role of nonfreezing water in the selective transport is discussed." @default.
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- W2023571487 date "2008-12-01" @default.
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- W2023571487 title "Modifying microphase separation of PVA based membranes for improving proton/methanol selectivity" @default.
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- W2023571487 doi "https://doi.org/10.1016/j.desal.2007.09.029" @default.
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