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- W2023573682 abstract "The complexation of di-(2-pyridylmethyl)amine to RuHCl(PPh3)3 affords the salt [RuH{κ3N-fac-1,3-di-(2-pyridylmethyl)amine}(PPh3)2]Cl. Reaction with potassium tert-butoxide at room temperature yields the unusual ruthenaziridine complex RuH{κ3CalkNNpy-1,3-di-(2-pyridylmethyl)amine}(PPh3)2, where the central nitrogen atom, adjacent alkyl carbon, and pyridine arm coordinate to the metal, leaving the second pyridine arm uncoordinated. Surprisingly, heating of this ruthenaziridine complex with concomitant H2 formation affords the ruthenium azaallyl complex RuH(κ3N-1,3-di-(2-pyridyl)-2-azaallyl)(PPh3)2. This is a rare example of a 4d metal complex containing the azaallyl ligand. X-Ray crystal structures and NMR characterization of all three compounds are presented herein." @default.
- W2023573682 created "2016-06-24" @default.
- W2023573682 creator A5039634682 @default.
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- W2023573682 date "2011-01-01" @default.
- W2023573682 modified "2023-10-02" @default.
- W2023573682 title "From amine to ruthenaziridine to azaallyl: unusual transformation of di-(2-pyridylmethyl)amine on ruthenium" @default.
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- W2023573682 doi "https://doi.org/10.1039/c1dt10626k" @default.
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