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- W2023574108 abstract "Biomass-nitrogen conversion during the pyrolysis and gasification of a cane trash in steam was investigated using a fluidised-bed/fixed-bed reactor and a fluidised-bed/tubular reactor. Our results indicate that the thermal cracking of volatile-N is the main route of HCN formation although the thermal cracking of char-N also contributes to the formation of HCN. There are three major routes of NH3 formation: ‘hydrolysis’ of N-containing structures in the solid phase during the primary pyrolysis, thermal cracking and gasification of solid nascent char as well as the thermal cracking and reforming of volatile-N. Under the current experimental conditions, the hydrolysis of HCN does not appear to be an important route of NH3/HNCO formation." @default.
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- W2023574108 date "2005-03-01" @default.
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- W2023574108 title "Formation of NO precursors during the pyrolysis of coal and biomass. Part VII. Pyrolysis and gasification of cane trash with steam" @default.
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- W2023574108 doi "https://doi.org/10.1016/j.fuel.2004.09.018" @default.
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