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- W2023574129 abstract "Ionized cyclopentanol and [C5H10O]+˙ ions with the oxygen on the first carbon lose methyl, ethylene, ethyl, ethane and water in their metastable decompositions. We show by collisionally activated decompositions of the products that the losses of ethyl form CH3CH2CO+, the losses of ethylene form , and the losses of methyl probably yield . Deuterium labeling indicates that ethyl loss from ionized cyclopentanol occurs following α-cleavage of the ring, isomerization to the enol isomer of ionized n-pentanal and subsequent isomerization to the 3-pentanone ion." @default.
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- W2023574129 date "1984-01-01" @default.
- W2023574129 modified "2023-09-23" @default.
- W2023574129 title "Metastable decompositions of cyclopentanol ions and [C5H10O]+˙ ions with the oxygen on the first carbon" @default.
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- W2023574129 doi "https://doi.org/10.1002/oms.1210190102" @default.
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