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- W2023574994 abstract "Abstract The behavior of Rh supported on TiO2 has been studied as a function of oxidation and reduction temperature. Infrared spectroscopy of adsorbed CO and OH and X-ray photoelectron spectroscopy of Rh demonstrate the strong dependence of chemisorbed CO on the oxidation state of Rh and the importance of OH on TiO2 in controlling the Rh dispersion process. Carbon monoxide exposure induces oxidative disruption of metallic Rh clusters at temperatures as low as 160 K. At temperatures above 473 K, CO exposure leads to reduction of oxidized Rh." @default.
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- W2023574994 title "CO-induced structural changes of Rh on TiO2 Support" @default.
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