FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023579697> ?p ?o ?g. }

• W2023579697 endingPage "9156" @default.
• W2023579697 startingPage "9154" @default.
• W2023579697 abstract "Salt metathesis reactions of Cp(2)(NR(2))ZrX (X = Cl, I, OTf) and lithium hydrosilazides ultimately afford hydride products Cp(2)(NR(2))ZrH that suggest unusual β-hydrogen elimination processes. A likely intermediate in one of these reactions, Cp(2)Zr[N(SiHMe(2))t-Bu][N(SiHMe(2))(2)], is isolated under controlled synthetic conditions. Addition of alkali metal salts to this zirconium hydrosilazide compound produces the corresponding zirconium hydride. However as conditions are varied, a number of other pathways are also accessible, including C-H/Si-H dehydrocoupling, γ-abstraction of a CH, and β-abstraction of a SiH. Our observations suggest that the conversion of (hydrosilazido)zirconocene to zirconium hydride and silanimine does not follow the classical four-center mechanism for β-elimination." @default.
• W2023579697 created "2016-06-24" @default.
• W2023579697 creator A5015422195 @default.
• W2023579697 creator A5035390856 @default.
• W2023579697 creator A5055368311 @default.
• W2023579697 date "2012-05-23" @default.
• W2023579697 modified "2023-09-30" @default.
• W2023579697 title "Nonclassical β-Hydrogen Elimination of Hydrosilazido Zirconium Compounds via Direct Hydrogen Transfer" @default.
• W2023579697 cites W1945346766 @default.
• W2023579697 cites W1963811478 @default.
• W2023579697 cites W1966508281 @default.
• W2023579697 cites W1969694867 @default.
• W2023579697 cites W1979464624 @default.
• W2023579697 cites W1981730841 @default.
• W2023579697 cites W1982791686 @default.
• W2023579697 cites W1983512172 @default.
• W2023579697 cites W1988757450 @default.
• W2023579697 cites W1991205694 @default.
• W2023579697 cites W1994253833 @default.
• W2023579697 cites W1994876612 @default.
• W2023579697 cites W1998411021 @default.
• W2023579697 cites W2002858366 @default.
• W2023579697 cites W2004957923 @default.
• W2023579697 cites W2006395860 @default.
• W2023579697 cites W2008550382 @default.
• W2023579697 cites W2012656110 @default.
• W2023579697 cites W2015741815 @default.
• W2023579697 cites W2020231361 @default.
• W2023579697 cites W2040921452 @default.
• W2023579697 cites W2041086195 @default.
• W2023579697 cites W2042961961 @default.
• W2023579697 cites W2049032874 @default.
• W2023579697 cites W2064730371 @default.
• W2023579697 cites W2068988456 @default.
• W2023579697 cites W2069964381 @default.
• W2023579697 cites W2076568297 @default.
• W2023579697 cites W2078576504 @default.
• W2023579697 cites W2081113991 @default.
• W2023579697 cites W2085949732 @default.
• W2023579697 cites W2093705743 @default.
• W2023579697 cites W2094947909 @default.
• W2023579697 cites W2095372317 @default.
• W2023579697 cites W2123372163 @default.
• W2023579697 cites W2171635127 @default.
• W2023579697 cites W2950236762 @default.
• W2023579697 cites W2952971329 @default.
• W2023579697 cites W2953222240 @default.
• W2023579697 doi "https://doi.org/10.1021/ja302226c" @default.
• W2023579697 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22620714" @default.
• W2023579697 hasPublicationYear "2012" @default.
• W2023579697 type Work @default.
• W2023579697 sameAs 2023579697 @default.
• W2023579697 citedByCount "23" @default.
• W2023579697 countsByYear W20235796972012 @default.
• W2023579697 countsByYear W20235796972013 @default.
• W2023579697 countsByYear W20235796972014 @default.
• W2023579697 countsByYear W20235796972016 @default.
• W2023579697 countsByYear W20235796972017 @default.
• W2023579697 countsByYear W20235796972018 @default.
• W2023579697 countsByYear W20235796972021 @default.
• W2023579697 countsByYear W20235796972022 @default.
• W2023579697 countsByYear W20235796972023 @default.
• W2023579697 crossrefType "journal-article" @default.
• W2023579697 hasAuthorship W2023579697A5015422195 @default.
• W2023579697 hasAuthorship W2023579697A5035390856 @default.
• W2023579697 hasAuthorship W2023579697A5055368311 @default.
• W2023579697 hasBestOaLocation W20235796972 @default.
• W2023579697 hasConcept C134018914 @default.
• W2023579697 hasConcept C153914509 @default.
• W2023579697 hasConcept C155647269 @default.
• W2023579697 hasConcept C178790620 @default.
• W2023579697 hasConcept C179104552 @default.
• W2023579697 hasConcept C185592680 @default.
• W2023579697 hasConcept C198091228 @default.
• W2023579697 hasConcept C2776371256 @default.
• W2023579697 hasConcept C2777961443 @default.
• W2023579697 hasConcept C2778541603 @default.
• W2023579697 hasConcept C2778859185 @default.
• W2023579697 hasConcept C44138296 @default.
• W2023579697 hasConcept C44228677 @default.
• W2023579697 hasConcept C512968161 @default.
• W2023579697 hasConcept C521977710 @default.
• W2023579697 hasConcept C534791751 @default.
• W2023579697 hasConcept C71924100 @default.
• W2023579697 hasConcept C81022585 @default.
• W2023579697 hasConceptScore W2023579697C134018914 @default.
• W2023579697 hasConceptScore W2023579697C153914509 @default.
• W2023579697 hasConceptScore W2023579697C155647269 @default.
• W2023579697 hasConceptScore W2023579697C178790620 @default.
• W2023579697 hasConceptScore W2023579697C179104552 @default.
• W2023579697 hasConceptScore W2023579697C185592680 @default.
• W2023579697 hasConceptScore W2023579697C198091228 @default.
• W2023579697 hasConceptScore W2023579697C2776371256 @default.
• W2023579697 hasConceptScore W2023579697C2777961443 @default.
• W2023579697 hasConceptScore W2023579697C2778541603 @default.
• W2023579697 hasConceptScore W2023579697C2778859185 @default.
• W2023579697 hasConceptScore W2023579697C44138296 @default.
• W2023579697 hasConceptScore W2023579697C44228677 @default.

• next