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- W2023581630 abstract "The sorption of inorganic phosphate (P) by soils and hydrous ferric oxides was studied at times up to 192h. An initially rapid decrease in solution P concentration was followed by a much slower decrease between 48 and 192h with soils, Fe gel. and natural goethite, whereas synthetic goethite gave a well-defined equilibrium condition after only 48h. Resolution of the sorption isotherms showed that the increase in P sorption with time involved an appreciable shift of P from a more-physically sorbed form to a chemisorbed form. This was supported by chemical fractionation which showed that NaOH-extractable P was fairly constant with increasing sorption time, whereas the additional sorbed P was extracted by citrate-dithionite-bicarbonate from soils, and by HC1 from Fe gel and natural goethite. These sorbents contained short-range (amorphous) material, whereas synthetic goethite, from which all sorbed P was NaOH –extractable. did not. It is proposed that the time-dependent sorption of P and the associated shift of P to chemisorbed forms, involves the diffusion of P into “structurally porous”, short-range order material." @default.
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- W2023581630 date "1977-12-01" @default.
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- W2023581630 title "TIME-DEPENDENT SORPTION OF PHOSPHATE BY SOILS AND HYDROUS FERRIC OXIDES" @default.
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- W2023581630 doi "https://doi.org/10.1111/j.1365-2389.1977.tb02266.x" @default.
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