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- W2023585423 abstract "Abstract Oxidative coupling of methane to C 2 -hydrocarbons over MgO, Li MgO, MnO x MgO, Li MnO x MgO, CdO MgO, Li CdO MgO, ZnO MgO and Li ZnO MgO catalysts at 823–1103 K in presence of free oxygen has been investigated. The C 2 -selectivity of the catalysts and the ethylene-to-ethane ratio in the products were found to increase with the increase in the reaction temperature. The addition of lithium, zinc and cadmium promoters to MgO caused a very significant catalyst sintering resulting in a decrease in the catalyst surface area but an increase in the catalyst C 2 -selectivity. The catalyst C 2 -selectivity was found to be increased almost linearly with the decrease in the catalyst surface area. The lithium-promoted catalysts, however, showed a strong dependence of their methane conversion activity and C 2 -selectivity on the time on-stream and are sintered extensively during the catalytic process. Among the catalysts, the Li ZnO MgO and Li CdO MgO showed superior performance in the methane conversion process." @default.
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- W2023585423 date "1990-06-01" @default.
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- W2023585423 title "Oxidative conversion of methane to C2-hydrocarbons over lithium, manganese, cadmium and zinc promoted MgO catalysts I. Catalyst performance in presence of free oxygen" @default.
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- W2023585423 doi "https://doi.org/10.1016/s0166-9834(00)82246-0" @default.
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