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- W2023593221 abstract "3-(S)-(1-phenylethyl)-5-methyl- and 5-phenyl-rhodanine have been studied by single crystal X-ray crystallography. The crystals of the 5-methyl compound were shown to contain equal amounts of the 5-(R) and 5-(S) diastereomers, while the crystals of the 5-phenyl compound only contain the 5-(S) diastereomer. The UV and CD spectra of the 5-H2 compound have been analyzed on the basis of CNDO/S calculations, and the CD spectrum has been reproduced by semiempirical calculations.The 5-methyl diastereomers can be partly separated by chromatography on triacetylcellulose, and the CD spectra of the individual forms can be evaluated. The 5-phenyl compound undergoes rapid epimerization in solution, and also for this compound the CD spectra of both forms can be evaluated. The contribution of the 5-substituent follows Ripperger's sector rule for dithiocarbamates. Chirality 9:568–577, 1997. © 1997 Wiley-Liss, Inc." @default.
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- W2023593221 date "1997-01-01" @default.
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- W2023593221 title "Diastereomers of 3-(S)-(1-phenylethyl)-5-methyl- and -5-phenylrhodanine: Crystal structures, conformations, and circular dichroism spectra" @default.
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- W2023593221 doi "https://doi.org/10.1002/(sici)1520-636x(1997)9:5/6<568::aid-chir26>3.0.co;2-l" @default.
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