Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023593874> ?p ?o ?g. }
- W2023593874 endingPage "4770" @default.
- W2023593874 startingPage "4759" @default.
- W2023593874 abstract "The reactions of allene, methylallene, and 1,1-dimethylallene with [RhM(CO)4(μ-CH2)(dppm)2][X] (M = Os, X = BF4 (1); M = Ru, X = CF3SO3 (3); dppm = μ-Ph2PCH2PPh2) in the presence of 1 equiv of trimethylamine oxide yield a variety of products. Under these conditions compounds 1 and 3 react with allene to yield the trimethylenemethane-bridged products [RhM(CO)2(μ-η3:η1-C(CH2)3)(dppm)2][X] (M = Os (5), Ru (6)), in which the trimethylenemethane fragment is η1-bound to the group 8 metal by one methylene group and η3-bound to Rh by the rest of the fragment. These compounds react with CO and PMe3 to yield [RhM(CO)2L(μ-η3:η1-C(CH2)3)(dppm)2][X] (L = CO, PMe3), in which L is coordinated to Rh and the η3:η1-binding mode of trimethylenemethane is retained. Although attack of L occurs at Rh for the Rh/Ru species, carbonyl attack in the Rh/Os compound initially occurs at Os with subsequent scrambling throughout the three carbonyl sites; attack of PMe3 on the Rh/Os compound occurs at Rh. Methylallene reacts with 1 and ..." @default.
- W2023593874 created "2016-06-24" @default.
- W2023593874 creator A5004049595 @default.
- W2023593874 creator A5032259302 @default.
- W2023593874 creator A5045248437 @default.
- W2023593874 creator A5050325402 @default.
- W2023593874 creator A5088713964 @default.
- W2023593874 date "2004-09-01" @default.
- W2023593874 modified "2023-10-14" @default.
- W2023593874 title "Carbon−Carbon Bond Formation by Cumulene Insertion into “Rh(μ-CH<sub>2</sub>)M” Moieties (M = Ru, Os): Roles of the Cumulenes and the Metals in Product Formation" @default.
- W2023593874 cites W1418803502 @default.
- W2023593874 cites W1964047650 @default.
- W2023593874 cites W1965965847 @default.
- W2023593874 cites W1969179959 @default.
- W2023593874 cites W1970656311 @default.
- W2023593874 cites W1977482657 @default.
- W2023593874 cites W1978040026 @default.
- W2023593874 cites W1978747619 @default.
- W2023593874 cites W1980049245 @default.
- W2023593874 cites W1983593327 @default.
- W2023593874 cites W1990356263 @default.
- W2023593874 cites W1991140523 @default.
- W2023593874 cites W1992055785 @default.
- W2023593874 cites W1992507238 @default.
- W2023593874 cites W1996118054 @default.
- W2023593874 cites W1997547848 @default.
- W2023593874 cites W1997920869 @default.
- W2023593874 cites W1998790627 @default.
- W2023593874 cites W1999554977 @default.
- W2023593874 cites W2007344394 @default.
- W2023593874 cites W2012479786 @default.
- W2023593874 cites W2012795503 @default.
- W2023593874 cites W2026698276 @default.
- W2023593874 cites W2031861401 @default.
- W2023593874 cites W2036096677 @default.
- W2023593874 cites W2038970394 @default.
- W2023593874 cites W2053545885 @default.
- W2023593874 cites W2055742551 @default.
- W2023593874 cites W2066315025 @default.
- W2023593874 cites W2071400028 @default.
- W2023593874 cites W2076019470 @default.
- W2023593874 cites W2076916466 @default.
- W2023593874 cites W2088492876 @default.
- W2023593874 cites W2092727040 @default.
- W2023593874 cites W2093622399 @default.
- W2023593874 cites W2135989843 @default.
- W2023593874 cites W2161241924 @default.
- W2023593874 cites W2279779346 @default.
- W2023593874 cites W2569525354 @default.
- W2023593874 cites W2951025547 @default.
- W2023593874 cites W2952574594 @default.
- W2023593874 cites W2952875958 @default.
- W2023593874 cites W2953345736 @default.
- W2023593874 cites W3004619850 @default.
- W2023593874 cites W3005077799 @default.
- W2023593874 cites W332695842 @default.
- W2023593874 doi "https://doi.org/10.1021/om040074+" @default.
- W2023593874 hasPublicationYear "2004" @default.
- W2023593874 type Work @default.
- W2023593874 sameAs 2023593874 @default.
- W2023593874 citedByCount "20" @default.
- W2023593874 countsByYear W20235938742012 @default.
- W2023593874 countsByYear W20235938742013 @default.
- W2023593874 countsByYear W20235938742016 @default.
- W2023593874 countsByYear W20235938742021 @default.
- W2023593874 crossrefType "journal-article" @default.
- W2023593874 hasAuthorship W2023593874A5004049595 @default.
- W2023593874 hasAuthorship W2023593874A5032259302 @default.
- W2023593874 hasAuthorship W2023593874A5045248437 @default.
- W2023593874 hasAuthorship W2023593874A5050325402 @default.
- W2023593874 hasAuthorship W2023593874A5088713964 @default.
- W2023593874 hasConcept C104779481 @default.
- W2023593874 hasConcept C140205800 @default.
- W2023593874 hasConcept C155647269 @default.
- W2023593874 hasConcept C159985019 @default.
- W2023593874 hasConcept C161790260 @default.
- W2023593874 hasConcept C178790620 @default.
- W2023593874 hasConcept C185592680 @default.
- W2023593874 hasConcept C192562407 @default.
- W2023593874 hasConcept C2524010 @default.
- W2023593874 hasConcept C2776458898 @default.
- W2023593874 hasConcept C2777164566 @default.
- W2023593874 hasConcept C2780696404 @default.
- W2023593874 hasConcept C2991667435 @default.
- W2023593874 hasConcept C32909587 @default.
- W2023593874 hasConcept C33923547 @default.
- W2023593874 hasConcept C71240020 @default.
- W2023593874 hasConcept C90673727 @default.
- W2023593874 hasConceptScore W2023593874C104779481 @default.
- W2023593874 hasConceptScore W2023593874C140205800 @default.
- W2023593874 hasConceptScore W2023593874C155647269 @default.
- W2023593874 hasConceptScore W2023593874C159985019 @default.
- W2023593874 hasConceptScore W2023593874C161790260 @default.
- W2023593874 hasConceptScore W2023593874C178790620 @default.
- W2023593874 hasConceptScore W2023593874C185592680 @default.
- W2023593874 hasConceptScore W2023593874C192562407 @default.
- W2023593874 hasConceptScore W2023593874C2524010 @default.
- W2023593874 hasConceptScore W2023593874C2776458898 @default.