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- W2023606795 abstract "The authors report the solution to the coupled nonlinear first-order partial differential equations representing the dynamics of photochemical reactions in systems essentially free from diffusion. No limitation regarding absorption of light by products of inert medium is assumed. These equations have been solved with the boundary condition that the species be uniformly distributed in the material prior to irradiation; the incident light may have an arbitrary time dependence. This analytical method of solution has been applied to photobleaching reactions described by various rate laws, where both reactants and products can absorb light. In addition, model systems in which the products absorb more than the reactants (photoantibleaching reactions) are also studied. An empirical procedure is introduced that accounts for changes in surface reflectance during the photoreaction in a satisfactory manner. Finally, a comparison is made with the corresponding equations describing photochemistry in perfectly stirred media." @default.
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- W2023606795 date "1988-08-01" @default.
- W2023606795 modified "2023-09-24" @default.
- W2023606795 title "Photochemistry in strongly absorbing media" @default.
- W2023606795 doi "https://doi.org/10.1021/j100328a023" @default.
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