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- W2023607094 abstract "Es werden einige 1.3-Diphenyl-imidazoliumsalze (6a–d) dargestellt und der Einfluß des Anions auf die Protonenbeweglichkeit diskutiert. Das Perchlorat 6a wird mit Phenylsenföl (Kalium-tert.-butylat) zu dem Betain 19, mit Quecksilbersalzen zu den Quecksilbersalz-Carben-Komplexen 12, 13 und 14 umgesetzt. Die Bildungsmechanismen von 12–14 werden diskutiert. Chemistry of Nucleophilic Carbenes, XX. HX-Elimination from 1,3-Diphenylimidazolium Salts. Mercury Salt Carbene Complexes Some 1,3-diphenylimidazolium salts (6a–d) are synthesized, and the influence of the anion on the mobility of the proton is discussed. The perchlorate 6a reacts with phenyl isothiocyanate to give the betaine 19, and the reaction of 6a with mercury salts results in the formation of the mercury salt carbene complexes 12, 13 and 14. The mechanisms of formation of 12–14 are discussed." @default.
- W2023607094 created "2016-06-24" @default.
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- W2023607094 date "1970-04-01" @default.
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- W2023607094 title "Chemie nucleophiler Carbene, XX HX‐Abspaltung aus 1.3‐Diphenyl‐imidazoliumsalzen. Quecksilbersalz‐Carben‐Komplexe" @default.
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- W2023607094 doi "https://doi.org/10.1002/cber.19701030407" @default.
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