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- W2023608376 abstract "Cinchona alkaloid catalysts in combination with air- and moisture-stable N-trifluoromethylthiophthalimide as electrophilic SCF3 source enabled the catalytic enantioselective trifluoromethylsulfenylation. Thus, a series of α-SCF3 esters that bear a quaternary carbon stereogenic center were obtained with excellent yield and enantioselectivity. Moreover, the products can be readily converted into valuable α-SCF3 β-hydroxyesters. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W2023608376 created "2016-06-24" @default.
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- W2023608376 date "2013-10-07" @default.
- W2023608376 modified "2023-10-18" @default.
- W2023608376 title "<i>N</i>-Trifluoromethylthiophthalimide: A Stable Electrophilic SCF<sub>3</sub>-Reagent and its Application in the Catalytic Asymmetric Trifluoromethylsulfenylation" @default.
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- W2023608376 doi "https://doi.org/10.1002/anie.201304957" @default.
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