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- W2023609906 abstract "Summary A new detection principle for high-performance liquid chromatography is described in which the separation column is coupled to a catalytic detection system. The catalytic reaction is based on the redox reaction between cerium(IV) and arsenic (III) that is catalyzed by trace amounts of iodine. The decoloration of cerium(IV) is measured spectrophotometrically at 365 nm. The reaction was studied for continuous operation using triiodothyronine as substrate. The speed of reaction was decreased by all of the organic solvents tested. The detection principle permits trace determinations of iodine-substituted molecules. The limits of detection for the hormones tetra- and triiodothyronine are in the sub-nanogram range, which should be sufficient for their determination in human plasma." @default.
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- W2023609906 date "1978-02-01" @default.
- W2023609906 modified "2023-09-25" @default.
- W2023609906 title "Catalytic detection principle for high-performance liquid chromatography" @default.
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- W2023609906 doi "https://doi.org/10.1016/s0021-9673(00)81021-3" @default.
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