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- W2023618183 abstract "The reduction of dissolved sulphur and the soluble species formed during the electrolysis of PbS dissolved in the PbCl2NaCl eutectic has been studied chronopotentiometrically. The pre-lead reduction process reported earlier[1] can now be assigned to a subsulphide species that is generated electrochemically. At higher PbS concentrations (eg 10−3 mol cm−3), elemental sulphur introduces a new reduction wave in addition to the subsulphide. The saturation solubility of sulphur is approximately proportional to the square of the PbS concentration. It has been estimated to be 2.3× 10−4 mol S cm−3 at 430°C for a melt containing 2.4× 10−3 mol PbS cm−3 in the PbCl2-NaCl eutectic." @default.
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- W2023618183 date "1980-02-01" @default.
- W2023618183 modified "2023-10-15" @default.
- W2023618183 title "Reduction of sulphur in PbSPbCl2NaCl melts" @default.
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- W2023618183 doi "https://doi.org/10.1016/0013-4686(80)80040-5" @default.
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