Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023631851> ?p ?o ?g. }
- W2023631851 endingPage "2631" @default.
- W2023631851 startingPage "2626" @default.
- W2023631851 abstract "Poly(diiododiacetylene) (PIDA), formed by the topochemical polymerization of diiodobutadiyne within host−guest cocrystals, is a conjugated polymer containing an all-carbon backbone and only iodine atom substituents. Extensive rinsing and sonication of the PIDA cocrystals in organic solvents such as methanol, THF, and chloroform yield fibrous materials with diameters as low as 10−50 nm. Raman spectroscopy and 13C MAS NMR confirm that these fibers contain PIDA but that the host has been removed. Polarized Raman scattering measurements indicate that the PIDA filaments are uniaxially oriented. The PIDA nanofibers are stable at room temperature when undisturbed but become explosive under external energy such as shock or pressure. They transform to sp2-hybridized carbon irreversibly at room temperature when irradiated with a 532 nm Raman laser beam. Under thermal conditions, the PIDA fibers start releasing iodine at 120 °C and undergo complete carbonization in 1 h by pyrolysis at 900 °C." @default.
- W2023631851 created "2016-06-24" @default.
- W2023631851 creator A5019997234 @default.
- W2023631851 creator A5022863079 @default.
- W2023631851 creator A5023711566 @default.
- W2023631851 creator A5040430480 @default.
- W2023631851 creator A5040552329 @default.
- W2023631851 creator A5046842097 @default.
- W2023631851 creator A5054402991 @default.
- W2023631851 creator A5061934854 @default.
- W2023631851 creator A5069456879 @default.
- W2023631851 creator A5088159296 @default.
- W2023631851 date "2011-03-25" @default.
- W2023631851 modified "2023-09-23" @default.
- W2023631851 title "Characterization and Carbonization of Highly Oriented Poly(diiododiacetylene) Nanofibers" @default.
- W2023631851 cites W1952898717 @default.
- W2023631851 cites W1968355863 @default.
- W2023631851 cites W1970497988 @default.
- W2023631851 cites W1973996346 @default.
- W2023631851 cites W1974021770 @default.
- W2023631851 cites W1975825463 @default.
- W2023631851 cites W1977087928 @default.
- W2023631851 cites W1980516378 @default.
- W2023631851 cites W1981457621 @default.
- W2023631851 cites W1983800634 @default.
- W2023631851 cites W1986825046 @default.
- W2023631851 cites W1997430627 @default.
- W2023631851 cites W2002143887 @default.
- W2023631851 cites W2018858346 @default.
- W2023631851 cites W2027892034 @default.
- W2023631851 cites W2037343346 @default.
- W2023631851 cites W2038313886 @default.
- W2023631851 cites W2045565501 @default.
- W2023631851 cites W2062982910 @default.
- W2023631851 cites W2079077506 @default.
- W2023631851 cites W2081028902 @default.
- W2023631851 cites W2102435805 @default.
- W2023631851 cites W2111519025 @default.
- W2023631851 cites W2115465710 @default.
- W2023631851 cites W2115940597 @default.
- W2023631851 cites W2146161411 @default.
- W2023631851 cites W2147278843 @default.
- W2023631851 cites W2159744437 @default.
- W2023631851 cites W2235679284 @default.
- W2023631851 cites W2952744162 @default.
- W2023631851 cites W91773989 @default.
- W2023631851 doi "https://doi.org/10.1021/ma102324r" @default.
- W2023631851 hasPublicationYear "2011" @default.
- W2023631851 type Work @default.
- W2023631851 sameAs 2023631851 @default.
- W2023631851 citedByCount "30" @default.
- W2023631851 countsByYear W20236318512012 @default.
- W2023631851 countsByYear W20236318512013 @default.
- W2023631851 countsByYear W20236318512014 @default.
- W2023631851 countsByYear W20236318512015 @default.
- W2023631851 countsByYear W20236318512016 @default.
- W2023631851 countsByYear W20236318512017 @default.
- W2023631851 countsByYear W20236318512018 @default.
- W2023631851 countsByYear W20236318512019 @default.
- W2023631851 countsByYear W20236318512020 @default.
- W2023631851 countsByYear W20236318512022 @default.
- W2023631851 crossrefType "journal-article" @default.
- W2023631851 hasAuthorship W2023631851A5019997234 @default.
- W2023631851 hasAuthorship W2023631851A5022863079 @default.
- W2023631851 hasAuthorship W2023631851A5023711566 @default.
- W2023631851 hasAuthorship W2023631851A5040430480 @default.
- W2023631851 hasAuthorship W2023631851A5040552329 @default.
- W2023631851 hasAuthorship W2023631851A5046842097 @default.
- W2023631851 hasAuthorship W2023631851A5054402991 @default.
- W2023631851 hasAuthorship W2023631851A5061934854 @default.
- W2023631851 hasAuthorship W2023631851A5069456879 @default.
- W2023631851 hasAuthorship W2023631851A5088159296 @default.
- W2023631851 hasConcept C120665830 @default.
- W2023631851 hasConcept C121332964 @default.
- W2023631851 hasConcept C127413603 @default.
- W2023631851 hasConcept C154877778 @default.
- W2023631851 hasConcept C159985019 @default.
- W2023631851 hasConcept C188027245 @default.
- W2023631851 hasConcept C192562407 @default.
- W2023631851 hasConcept C26771246 @default.
- W2023631851 hasConcept C40003534 @default.
- W2023631851 hasConcept C42360764 @default.
- W2023631851 hasConcept C44228677 @default.
- W2023631851 hasConcept C521977710 @default.
- W2023631851 hasConcept C59061564 @default.
- W2023631851 hasConceptScore W2023631851C120665830 @default.
- W2023631851 hasConceptScore W2023631851C121332964 @default.
- W2023631851 hasConceptScore W2023631851C127413603 @default.
- W2023631851 hasConceptScore W2023631851C154877778 @default.
- W2023631851 hasConceptScore W2023631851C159985019 @default.
- W2023631851 hasConceptScore W2023631851C188027245 @default.
- W2023631851 hasConceptScore W2023631851C192562407 @default.
- W2023631851 hasConceptScore W2023631851C26771246 @default.
- W2023631851 hasConceptScore W2023631851C40003534 @default.
- W2023631851 hasConceptScore W2023631851C42360764 @default.
- W2023631851 hasConceptScore W2023631851C44228677 @default.
- W2023631851 hasConceptScore W2023631851C521977710 @default.
- W2023631851 hasConceptScore W2023631851C59061564 @default.