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- W2023641429 abstract "The crystallographic data of YBa 2 Cu 3 O 7− δ , Y 2 BaCuO 5 , BaCu 2 O 2 , and YBa 4 Cu 3 O 9 at high temperatures and p (O2)<10 Pa have been derived on the basis of HT-XRD measurements. Whereas Y 2 BaCuO 5 expands nearly isotropically, YBa 2 Cu 3 O 7− δ and BaCu 2 O 2 show anisotropic expansions. Furthermore, the first decomposition step of the considered compounds at p (O 2 )<10 Pa was observed. BaCu 2 O 2 melts congruently at T ≍ 1273 K and Y 2 BaCuO 5 decomposes via a peritectic reaction into Y 2 O 3 , Y 2 BaO 4 and melts at T ≍ 1323 K. A solid-state reaction into Y 2 BaCuO 5 and BaCu 2 O 2 was indicated for YBa 2 Cu 3 O 7− δ at T ≍ 1123 K. Because YBa 4 Cu 3 O 9 becomes unstable at T ≍ 1123 K, this compound cannot be formed by the primary decomposition reaction of YBa 2 Cu 3 O 7− δ" @default.
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- W2023641429 date "1995-09-01" @default.
- W2023641429 modified "2023-09-28" @default.
- W2023641429 title "High temperature X-ray diffraction studies of the decomposition mechanism of YBa2Cu3O7−δ at an oxygen partial pressure less than 10 Pa" @default.
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- W2023641429 doi "https://doi.org/10.1017/s0885715600014652" @default.
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