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- W2023641870 abstract "A statistical analysis has been performed of the errors incident to the individual experimental parameters necessary for expressing the specific retention volume. A gas chromatograph, in which the working conditions can be controlled with a high accuracy, has been constructed. When using packed columns in this apparatus, the precision of a single measurement corresponds to a coefficient of variation of about 0.2%; with capillary columns the coefficient amounted to about 0.3%. The width of the confidence interval of te Vg obtained in two chromatographic runs was about ± ml/g, which corresponds to a resolving power of about 45,000 theoretical plates at a given relative retention. The reliability attained renders the Vg values useful for calculating the excess thermodynamic properties." @default.
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- W2023641870 title "High precision measurement of specific retention volumes" @default.
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