FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023644040> ?p ?o ?g. }

• W2023644040 endingPage "4275" @default.
• W2023644040 startingPage "4265" @default.
• W2023644040 abstract "22-Membered mercuraazametallamacrocycles 6, 7, and 12 have been synthesized by dipodal condensation (2 + 2) of bis(o-formylphenyl)mercury (11) and 1,2-disubstituted amines. Reduction of macrocycle 6 with sodium borohydride afforded novel 11-membered mercuraazametallamacrocycle 13. Macrocycle 6, when treated with [Cu(CH3CN)4]ClO4 and Cu(OCOCH3)2/NH4PF6, formed orange-colored CuI complexes 14 ([6·Cu]ClO4) and 15 ([6·Cu]PF6), respectively, whereas red-colored complex 16 ([12·Cu]ClO4) was obtained from the reaction of 12 with [Cu(CH3CN)4]ClO4. Similarly, complexes 17 ([6·Ag]ClO4) and 18 ([6·Ag]PF6) were synthesized by the reaction of 6 with the corresponding silver salts. The reaction of 6 with Hg(OCOCH3)2/NH4PF6 led to the formation of hydroxo-bridged complex 19. The reaction of macrocycle 7 with Pd(C6H5CN)2Cl2 gave access to novel complex 9a. The macrocycles and the complexes have been characterized by elemental analysis, NMR (1H, 13C, 199Hg), fluorescence spectroscopy, and cyclic voltammetry. The molecular structures of organomercury precursors Hg{1-C6H4-2-(CH2OH)}2 (10) and Hg{1-C6H4-2-(CHO)}2 (11) and macrocycles 6, 7, and 12 show almost linear geometry around mercury; however, 13 shows a bent structure, i.e., significant deviation of the C−Hg−C angle from linearity. 22-Membered mercuraazametallamacrocycles 6, 7, and 12 are stabilized by secondary Hg···N intramolecular interaction and have an “hour-glass”-like conformation. The molecular structures of 14, 17, and 9a showed metallophilic interactions. The metal ions (CuI and AgI) are coordinated not only to the four nitrogens but also to two mercury atoms, forming a distorted octahedral geometry around the metal ions." @default.
• W2023644040 created "2016-06-24" @default.
• W2023644040 creator A5013843123 @default.
• W2023644040 creator A5015793440 @default.
• W2023644040 creator A5023343074 @default.
• W2023644040 creator A5032666050 @default.
• W2023644040 creator A5043245954 @default.
• W2023644040 creator A5045505803 @default.
• W2023644040 creator A5080882260 @default.
• W2023644040 date "2010-09-09" @default.
• W2023644040 modified "2023-10-14" @default.
• W2023644040 title "Intermetallic Bonds in Metallophilic Mercuraazametallamacrocycles of Synthetic Design" @default.
• W2023644040 cites W1955376658 @default.
• W2023644040 cites W1963771858 @default.
• W2023644040 cites W1964573689 @default.
• W2023644040 cites W1965272987 @default.
• W2023644040 cites W1966224597 @default.
• W2023644040 cites W1966545431 @default.
• W2023644040 cites W1972583560 @default.
• W2023644040 cites W1973036992 @default.
• W2023644040 cites W1974453939 @default.
• W2023644040 cites W1984810307 @default.
• W2023644040 cites W1985366732 @default.
• W2023644040 cites W1985699741 @default.
• W2023644040 cites W1987698676 @default.
• W2023644040 cites W1989514402 @default.
• W2023644040 cites W1989914793 @default.
• W2023644040 cites W1989990860 @default.
• W2023644040 cites W1991091028 @default.
• W2023644040 cites W1991139785 @default.
• W2023644040 cites W1991506892 @default.
• W2023644040 cites W1996679083 @default.
• W2023644040 cites W1997382277 @default.
• W2023644040 cites W1998772016 @default.
• W2023644040 cites W1998952443 @default.
• W2023644040 cites W2000382601 @default.
• W2023644040 cites W2003071113 @default.
• W2023644040 cites W2008192551 @default.
• W2023644040 cites W2009907091 @default.
• W2023644040 cites W2010485565 @default.
• W2023644040 cites W2017266711 @default.
• W2023644040 cites W2017675618 @default.
• W2023644040 cites W2020693114 @default.
• W2023644040 cites W2021746019 @default.
• W2023644040 cites W2023900656 @default.
• W2023644040 cites W2025830867 @default.
• W2023644040 cites W2026372755 @default.
• W2023644040 cites W2030841140 @default.
• W2023644040 cites W2031839517 @default.
• W2023644040 cites W2033928246 @default.
• W2023644040 cites W2034856684 @default.
• W2023644040 cites W2035024385 @default.
• W2023644040 cites W2039072353 @default.
• W2023644040 cites W2044287989 @default.
• W2023644040 cites W2047879486 @default.
• W2023644040 cites W2050442557 @default.
• W2023644040 cites W2050540841 @default.
• W2023644040 cites W2052265901 @default.
• W2023644040 cites W2053453103 @default.
• W2023644040 cites W2056655922 @default.
• W2023644040 cites W2059033805 @default.
• W2023644040 cites W2071499832 @default.
• W2023644040 cites W2076750113 @default.
• W2023644040 cites W2077104340 @default.
• W2023644040 cites W2077366645 @default.
• W2023644040 cites W2077679334 @default.
• W2023644040 cites W2078818614 @default.
• W2023644040 cites W2078877422 @default.
• W2023644040 cites W2083995118 @default.
• W2023644040 cites W2085556928 @default.
• W2023644040 cites W2089469970 @default.
• W2023644040 cites W2091407593 @default.
• W2023644040 cites W2092507938 @default.
• W2023644040 cites W2096690326 @default.
• W2023644040 cites W2098163157 @default.
• W2023644040 cites W2099427463 @default.
• W2023644040 cites W2104745690 @default.
• W2023644040 cites W2114778982 @default.
• W2023644040 cites W2121237359 @default.
• W2023644040 cites W2123037660 @default.
• W2023644040 cites W2129522968 @default.
• W2023644040 cites W2136959483 @default.
• W2023644040 cites W2138857810 @default.
• W2023644040 cites W2139608693 @default.
• W2023644040 cites W2144486442 @default.
• W2023644040 cites W2146520439 @default.
• W2023644040 cites W2154684629 @default.
• W2023644040 cites W2154774781 @default.
• W2023644040 cites W2155304007 @default.
• W2023644040 cites W2181331932 @default.
• W2023644040 cites W2315234697 @default.
• W2023644040 cites W2316076727 @default.
• W2023644040 cites W2491755218 @default.
• W2023644040 cites W2950318600 @default.
• W2023644040 cites W2952024323 @default.
• W2023644040 cites W2952281906 @default.
• W2023644040 cites W4250574492 @default.
• W2023644040 doi "https://doi.org/10.1021/om100297v" @default.

• next