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- W2023648166 abstract "The effect of SO2−4, Cl− and I− ions on the anodic currents of the successive passivating processes that take place in alkaline phosphate solutions, on the above has been studied using potentiodynamic, galvanodynamic and open circuit potential measurements. Additions of I− resulted in the largest current increase followed by Cl−. Additions of SO42− showed an initial anodic current decrease, a trend that was reversed with the progress of cycle number. While the current increase, of Cu(1) oxide, with increasing halide additions, follows closely: δi=(A[X-1])(B+m[X-]) that of Cu(II) oxide process obeyed δi=A[X-] where Δi is the increase in peak current and [X−] the halide concentration added. A mechanism involving adsorption of the halide ions on the electrode surface and/or exchange with OH− attached to the soluble metal ion, is discussed." @default.
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- W2023648166 date "1982-01-01" @default.
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- W2023648166 title "Passivation of copper: Role of some anions in the mechanism of film formation and breakdown" @default.
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