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• W2023650166 abstract "Raman, IR, and visible absorption spectra of scandium trihydride (ScH${}_{3}$) have been measured at high pressures up to 50 GPa, to investigate the structural and electronic phase transitions. Successive hcp-intermediate-fcc phase transitions were observed at 25 and 46 GPa by Raman and IR measurements. It was suggested that the intermediate phase of ScH${}_{3}$ takes the same structure as that of YH${}_{3}$ with a long periodicity of the stacking of the metal planes. The visible absorption spectra allowed us to determine that the energy gap of ScH${}_{3}$ is 1.7 eV at the ambient condition and is closed around 50 GPa, at which the crystal structure transforms to fcc." @default.
• W2023650166 created "2016-06-24" @default.
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• W2023650166 date "2011-08-31" @default.
• W2023650166 modified "2023-10-07" @default.
• W2023650166 title "High-pressure study of ScH<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msub><mml:mrow /><mml:mn>3</mml:mn></mml:msub></mml:math>: Raman, infrared, and visible absorption spectroscopy" @default.
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• W2023650166 doi "https://doi.org/10.1103/physrevb.84.064132" @default.
• W2023650166 hasPublicationYear "2011" @default.
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