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- W2023651653 abstract "Abstract The synthesis of new chiral smectic A (S A ) side‐chain liquid crystalline polysiloxanes (LCPs) and ionomers (LCIs) containing 4‐allyloxy‐benzoyl‐4‐( S ‐2‐ethylhexanoyl) p ‐benzenediol bisate (ABB) as mesogenic units and 4‐[[4‐(2‐propenyloxy)phenyl]azo]benzenesulfonic acid (AABS) as nonmesogenic units is presented. The chemical structures of the monomers and polymers are confirmed by FTIR spectroscopy or 1 H–NMR. Differential scanning calorimetry (DSC), optical polarizing microscopy, and X‐ray diffraction measurements reveal that all the polymers P I –P IV and ionomers P V –P VI exhibit S A texture. The results seem to demonstrate that the tendency toward the S A ‐phase region increases with increasing sulfonic acid concentration, and the thermal stability of the S A phase is determined by the flexibility of the polymer backbones and the interactions of sulfonic acid groups. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 2335–2340, 2001" @default.
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- W2023651653 date "2001-03-26" @default.
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- W2023651653 title "Synthesis and characterization of chiral smectic side-chain liquid crystalline polysiloxanes and ionomers containing sulfonic acid groups" @default.
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- W2023651653 doi "https://doi.org/10.1002/app.1339" @default.
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