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- W2023658105 abstract "Abstract We measured the electron spin resonance and the magnetoresistance in the iron(III) phthalocyanine complexes. The electron spin resonance in PNP[Fe(Pc)(CN)2] reveals the large anisotropy of the g-value. This is due to the strong spin–orbit coupling in the second HOMO (the third HOMO) hybridizing the dyz (dzx) orbital in the central Fe atom. This anisotropic g-value is consistent with the anisotropy of the magnetic susceptibility and the negative magnetoresistance in TPP[Fe(Pc)(CN)2]2. We also measured the large negative magnetoresistance in [PXX][Fe(Pc)(CN)2] and (PTMA)x[Fe(Pc)(CN)2]Y(CH3CN). The iron(III) phthalocyanine complexes are the good materials for the research of the one-dimensional π–d electron system." @default.
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- W2023658105 date "2003-03-13" @default.
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- W2023658105 title "One-dimensional π–d electron system in TPP[Fe(Pc)(CN)2]2, [PXX][Fe(Pc)(CN)2], and (PTMA)x[Fe(Pc)(CN)2]Y(CH3CN): electron spin resonance and negative magnetoresistance" @default.
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- W2023658105 doi "https://doi.org/10.1016/s0379-6779(02)00429-0" @default.
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