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- W2023664023 abstract "The Ce(PO 3 ) 3 — AgPO 3 system was investigated by differential thermal analysis (DTA) and X-ray diffraction. Its phase equilibrium diagram was established by recording heating curves on a M5 Setaram μ-DTA aparatus. This diagram shows that the Ce (PO 3 ) 3 —AgPO 3 system forms only one compound, AgCe(PO 3 ) 4 , which melts in a peritectic reaction at 788°C. The chemical preparation, powder diagram and main crystallogrophic characteristics of this compound are given. AgCe(PO 3 ) 4 , a polyphosphate isotypic with NaNd(PO 3 ) 4 , has a monoclinic unit cell with a space group P2 1 n and parameters a = 9.717(4), b = 12.959(5), c = 7.242(2) Å, β = 91.07(2)°, Z = 4, V = 911.79 Å 3 , d x = 4.11. The different structure types of binary poly and metaphosphates, M 2 O.Ln 2 O 3 .4P 2 O 5 , are regrouped and a correlation between each crystalline form and the corresponding M 3 and Ln 3+ cation size is dicussed." @default.
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- W2023664023 date "1984-08-01" @default.
- W2023664023 modified "2023-09-26" @default.
- W2023664023 title "Diagramme d'equilibre solide-liquide du systeme Ce(PO3)3 — AgPO3" @default.
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- W2023664023 doi "https://doi.org/10.1016/0254-0584(84)90020-8" @default.
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