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• W2023671534 abstract "Abstract New A ‐site ordered perovskite structure oxides, CaCu 3 Fe 4 O 12 and LaCu 3 Fe 4 O 12 , were synthesized under high‐pressure and high‐temperature conditions. The compounds contain unusually high valence states of iron: Fe 4+ in CaCu 3 Fe 4 O 12 and Fe 3.75+ in LaCu 3 Fe 4 O 12 . Instabilities of the high oxidation states at low temperatures are resolved in CaCu 3 Fe 4 O 12 by charge disproportionation from Fe 4+ to Fe 3+ and Fe 5+ and in LaCu 3 Fe 4 O 12 by charge transfer between A ‐site copper and B ‐site iron ions. The charge disproportionation and the charge transfer are accompanied by significant changes in structural, transport, and magnetic properties." @default.
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• W2023671534 date "2009-10-01" @default.
• W2023671534 modified "2023-10-10" @default.
• W2023671534 title "Charge Disproportionation and Charge Transfer in<i>A</i>-site Ordered Perovskites Containing Iron" @default.
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• W2023671534 doi "https://doi.org/10.1002/zaac.200900248" @default.
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