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- W2023675511 abstract "The synthesis of acylketene 0,5-dialkyl acetals 2 a-p and acylketene O-aryl S-alkyl acetals 6 a-i is described. The compounds 2a-n are obtained by base-catalyzed alkylation of the respective β-oxo thiono esters 4 a-n prepared by alkoxythiocarbonylation of active methylene ketones in the presence of sodium tert-butoxide. The corresponding O-dodecanyl 2o, O-benzyl 2p and O-aryl, S-methyl 6a-i acetals are synthesized via base-catalyzed displacement of the sulfonium salts 5a-b with the corresponding alkanol or phenol" @default.
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- W2023675511 date "2010-08-20" @default.
- W2023675511 modified "2023-09-26" @default.
- W2023675511 title "ChemInform Abstract: Synthesis of α-Oxoketene O-Alkyl/Aryl, S-Alkyl Acetals." @default.
- W2023675511 cites W2951945373 @default.
- W2023675511 doi "https://doi.org/10.1002/chin.199326107" @default.
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