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- W2023676131 abstract "General methods for the preparation of a variety of 1-substituted vinyl-2-pyridones are described. Synthetic routes followed involve (1) nucleophilic substitution reaction of the 2-hydroxy-pyridyl anion of haloolefins containing β-activating groups, such as carbonyl and phenyl, (2) elimination reactions of ester derivatives of 1-pyridonyl-2-ethanols and (3) base catalyzed isomerizations of 1-allyl-2-pyridones. The details involved with each of the synthetic methods and purification of the derived 1-vinyl-2-pyridones are described. Additionally important spectroscopic properties of compounds in this series are discussed in terms of preferred conformations about the nitrogen-exocyclic vinyl carbon bond." @default.
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- W2023676131 date "1978-01-01" @default.
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- W2023676131 title "General synthetic methods for the preparation of 1-substituted-vinyl-2-pyridones" @default.
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- W2023676131 doi "https://doi.org/10.1016/0040-4020(78)88395-1" @default.
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