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- W2023676293 abstract "Abstract Vaporization of (molybdenum + tellurium) alloys was studied by Knudsen-effusion mass spectrometry. The partial pressures of Te2(g) and Te(g) over the two-phase field (Mo3Te4+MoTe2) were determined in the temperature range T = 820 K to 950 K. The boundaries of the Mo3Te4 phase were delineated by a continuous monitoring of the intensity of Te+2 as a function of time, starting with samples having mass fractions 0.67187 and 0.68997 of Te. The phase-boundary compositions correspond to MoTe1.10±0.03 (Mo-rich boundary) and MoTe1.30±0.04 (Te-rich boundary), respectively. By employing the p(Te2) determined as a function of composition, activities of Te were obtained; and by a Gibbs-Duhem integration, those of Mo were also computed at various compositions within the single-phase Mo3Te4. Our previously published p (Te2) and p(Te2) over (Mo+Mo3Te4) (J. Chem. Thermodynamics1989, 21, 1183) were used to obtain revised enthalpy changes for the reactions: MoTev(s) = Mo(s)+(v/i)Tei(g), where i = 1 or 2, and v = 1.10, the Mo-rich boundary composition of Mo3Te4 determined in this work. The standard molar enthalpies of formation of MoTe1.10 and MoTe1.30 (Mo- and Te-rich boundaries of the Mo3Te4 phase) as well as of MoTe1.89 (Mo-rich boundary of the α-modification of the MoTe2 phase) were derived." @default.
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- W2023676293 date "1993-04-01" @default.
- W2023676293 modified "2023-09-27" @default.
- W2023676293 title "Study of (molybdenum + tellurium) by Knudsen-effusion mass spectrometry" @default.
- W2023676293 doi "https://doi.org/10.1006/jcht.1993.1162" @default.
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