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- W2023678462 abstract "In this report, for the first time, a planar chiral photoresponsive compound has been employed in commercially available nematic liquid crystals to achieve phototunable reflection colors. We designed an azobenzenophane compound having conformational restriction on the free rotation of naphthalene moiety to impose an element of planar chirality and the corresponding enantiomers were resolved by HPLC on chiral column. We have determined the absolute configuration by comparison of density functional theory (DFT) calculations of its electronic circular dichroism (ECD) spectrum and specific rotation [α]D to experimental ECD and [α]D data. Enantiomers exhibit photochemically reversible isomerization in solution without undergoing thermal or photoinduced racemization. As chiroptic switches in different host nematic liquid crystals, they exhibit good solubility, moderately high helical twisting power, as well as a large change in helical twisting power due to photoisomerization. A unique feature of these chiral photochromic compounds is that no other auxiliary chiral agents is required to achieve a fast photon mode reversible full-range color control in induced cholesterics, that is, both the hypsochromic and bathochromic shift can be obtained from a single LC formulation by reversible photoisomerization of the single chiral compound." @default.
- W2023678462 created "2016-06-24" @default.
- W2023678462 creator A5032757204 @default.
- W2023678462 creator A5085049184 @default.
- W2023678462 date "2008-08-02" @default.
- W2023678462 modified "2023-10-13" @default.
- W2023678462 title "Planar Chiral Azobenzenophanes as Chiroptic Switches for Photon Mode Reversible Reflection Color Control in Induced Chiral Nematic Liquid Crystals" @default.
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- W2023678462 cites W1965668217 @default.
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- W2023678462 cites W1971719359 @default.
- W2023678462 cites W1975865701 @default.
- W2023678462 cites W1976436799 @default.
- W2023678462 cites W1983496476 @default.
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- W2023678462 doi "https://doi.org/10.1021/ja802472t" @default.
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