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- W2023679538 abstract "The electrical conductance of single n-alkanethiol and α,ω-alkanedithiol molecules was measured via in situ distance tunneling spectroscopy in aqueous 0.1 M KOH solution. The statistical analysis of the conductance values show that the α,ω-alkanedithiol molecule trapped in the STM break junction can adopt two distinct geometries that result in “lower” and “higher” conductivity values. In contrast, n-alkanethiol molecules trapped in the junction show only a single conductivity value characteristic for a particular molecule. Furthermore, the “lower” conductivity value determined for α,ω-alkanedithiol is virtually identical to the electrical conductivity of the n-alkanethiol containing the same number of atoms in the backbone. Moreover when the STM tip is polarized to electrochemical potential preventing a chemical reaction between the terminal −SH group and Au, only “lower” conductivity values are observed for α,ω-alkaneditiols." @default.
- W2023679538 created "2016-06-24" @default.
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- W2023679538 date "2006-05-13" @default.
- W2023679538 modified "2023-09-26" @default.
- W2023679538 title "In Situ Wiring of Single Molecules into an Electrical Circuit via Electrochemical Distance Tunneling Spectroscopy" @default.
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- W2023679538 doi "https://doi.org/10.1021/la060814e" @default.
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