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- W2023680061 abstract "The λ3P,λ5P-fluorophosphorane (1) involves a λ3 phosphorus atom directly linked to a λ5P phosphorus atom. It is therefore of interest whether the coordinating ability of the λ3 phosphorus atom in1 is affected by the directly bonded λ5 phosphorus atom. A number of complexes of1 were prepared with rhodium(I), iridium(I), and platinum(II).1 Was found to display normal ligand behaviour. Compounds were characterized especially by NMR-spectroscopy (1H,19F,31P) and, in the case of the complex (nBu3P)·(1)·PtCl2,8b, by a single-crystal X-ray diffraction study. The PP bond length is 226.6 pm, compared to 226.7 pm in the free ligand. Slight distortions from square planar coordination of platinum are observed." @default.
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- W2023680061 date "1994-03-01" @default.
- W2023680061 modified "2023-09-27" @default.
- W2023680061 title "Complexes of rhodium(I), platinum(II) and iridium(I) involving a mixed-valence diphosphorus ligand" @default.
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- W2023680061 doi "https://doi.org/10.1016/s0277-5387(00)83035-1" @default.
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