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- W2023683688 abstract "Abstract The first highly stereoselective and facile synthesis ofα‐trichloromethylamines is described by using a nucleophilic trichloromethylation strategy. With tetrabutylammonium triphenyldifluorosilicate (TBAT) as the mediator, the trichloromethyl anion (CCl 3 – ) from TMSCCl 3 can be transferred to N ‐( tert ‐butylsulfinyl)aldimines in excellent yields and with high diastereoselectivity (≥99:1 dr )." @default.
- W2023683688 created "2016-06-24" @default.
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- W2023683688 date "2010-12-17" @default.
- W2023683688 modified "2023-10-09" @default.
- W2023683688 title "Highly Stereoselective Trichloromethylation of <i>N</i>‐(<i>tert</i>‐Butylsulfinyl)aldimines: Facile Synthesis of Chiral α‐Trichloromethylamines" @default.
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- W2023683688 doi "https://doi.org/10.1002/ejoc.201001495" @default.
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