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• W2023687841 abstract "The reduction and subsequent oxidation of Ag(I)-containing films of polyfluorocarbon sulfonic acid (Nafion) have been studied spectroscopically, electron microscopically, and kinetically. The ultraviolet-visible and infrared spectral features observed in situ during these processes are interpreted in terms of the formation of Ag particles and their surface oxidation upon exposure to air or oxygen. The particle size distributions are narrow and give average diameters of 20–30 Å for various reductive and oxidative treatments. The kinetics of the oxidation, which were followed by observing the growth of silver-silver oxide charge transfer absorption at 370 nm, are analyzed in terms of two parallel reactions. The first, postulated to give atomically adsorbed oxygen, is about 10 times faster than the postulated slower formation of molecularly adsorbed oxygen." @default.
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• W2023687841 date "1985-06-01" @default.
• W2023687841 modified "2023-09-24" @default.
• W2023687841 title "Oxygen adsorption on silver in polyfluorocarbon sulfonic acid (Nafion) films" @default.
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• W2023687841 doi "https://doi.org/10.1016/0021-9517(85)90190-3" @default.
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