Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023689235> ?p ?o ?g. }
- W2023689235 endingPage "5055" @default.
- W2023689235 startingPage "5047" @default.
- W2023689235 abstract "The dissociative chemisorption of cyclobutane on the Ru(001) surface has been studied using thermal desorption spectroscopy (TDS) and high-resolution electron energy loss spectroscopy (HREELS). Two distinct methodologies have been used to study this reaction. First, we investigated the trapping-mediated reaction by exposing the surface to cyclobutane at 180 K. Second, although an adsorbed monolayer of cyclobutane undergoes nearly complete desorption during subsequent heating, we find that the presence of the condensed multilayer induces significant reaction. Using HREELS we find that both reaction channels yield a common intermediate which we identify to be a C4H8 metallacycle. At moderate and high surface coverages, a small amount of butene from the isomerization of the metallacycle desorbs between 185 and 225 K. Following the desorption of butene, we observe a hydrocarbon fragment on the surface which is tentatively identified to be a C4H4 metallacycle." @default.
- W2023689235 created "2016-06-24" @default.
- W2023689235 creator A5004948992 @default.
- W2023689235 creator A5023609721 @default.
- W2023689235 creator A5028792106 @default.
- W2023689235 date "1999-05-14" @default.
- W2023689235 modified "2023-09-26" @default.
- W2023689235 title "Trapping-Mediated and Multilayer-Induced Dissociative Chemisorption of Cyclobutane on Ru(001)" @default.
- W2023689235 cites W1966944082 @default.
- W2023689235 cites W1971091592 @default.
- W2023689235 cites W1972360986 @default.
- W2023689235 cites W1981379193 @default.
- W2023689235 cites W1982589349 @default.
- W2023689235 cites W1991267592 @default.
- W2023689235 cites W1994213387 @default.
- W2023689235 cites W1998574554 @default.
- W2023689235 cites W1999010008 @default.
- W2023689235 cites W2009829472 @default.
- W2023689235 cites W2010092005 @default.
- W2023689235 cites W2017433374 @default.
- W2023689235 cites W2020263629 @default.
- W2023689235 cites W2029613513 @default.
- W2023689235 cites W2030207335 @default.
- W2023689235 cites W2033386431 @default.
- W2023689235 cites W2036351026 @default.
- W2023689235 cites W2036863855 @default.
- W2023689235 cites W2037861862 @default.
- W2023689235 cites W2042279641 @default.
- W2023689235 cites W2042487847 @default.
- W2023689235 cites W2043049883 @default.
- W2023689235 cites W2043452622 @default.
- W2023689235 cites W2044147927 @default.
- W2023689235 cites W2047945208 @default.
- W2023689235 cites W2048651192 @default.
- W2023689235 cites W2059752589 @default.
- W2023689235 cites W2060557661 @default.
- W2023689235 cites W2062338601 @default.
- W2023689235 cites W2066343137 @default.
- W2023689235 cites W2067239023 @default.
- W2023689235 cites W2067896768 @default.
- W2023689235 cites W2078363688 @default.
- W2023689235 cites W2084573108 @default.
- W2023689235 cites W2091738133 @default.
- W2023689235 cites W2120899721 @default.
- W2023689235 cites W2155386179 @default.
- W2023689235 cites W2321230624 @default.
- W2023689235 cites W2327901852 @default.
- W2023689235 cites W2949962129 @default.
- W2023689235 cites W2950766013 @default.
- W2023689235 cites W2951650075 @default.
- W2023689235 cites W2952815280 @default.
- W2023689235 cites W3005213102 @default.
- W2023689235 cites W3005405449 @default.
- W2023689235 cites W3005511825 @default.
- W2023689235 cites W3024816394 @default.
- W2023689235 doi "https://doi.org/10.1021/ja983482b" @default.
- W2023689235 hasPublicationYear "1999" @default.
- W2023689235 type Work @default.
- W2023689235 sameAs 2023689235 @default.
- W2023689235 citedByCount "7" @default.
- W2023689235 countsByYear W20236892352012 @default.
- W2023689235 countsByYear W20236892352013 @default.
- W2023689235 crossrefType "journal-article" @default.
- W2023689235 hasAuthorship W2023689235A5004948992 @default.
- W2023689235 hasAuthorship W2023689235A5023609721 @default.
- W2023689235 hasAuthorship W2023689235A5028792106 @default.
- W2023689235 hasConcept C120665830 @default.
- W2023689235 hasConcept C121332964 @default.
- W2023689235 hasConcept C126661725 @default.
- W2023689235 hasConcept C135361552 @default.
- W2023689235 hasConcept C146088050 @default.
- W2023689235 hasConcept C147789679 @default.
- W2023689235 hasConcept C150394285 @default.
- W2023689235 hasConcept C155916967 @default.
- W2023689235 hasConcept C161790260 @default.
- W2023689235 hasConcept C162711632 @default.
- W2023689235 hasConcept C171250308 @default.
- W2023689235 hasConcept C178187954 @default.
- W2023689235 hasConcept C178790620 @default.
- W2023689235 hasConcept C185544564 @default.
- W2023689235 hasConcept C185592680 @default.
- W2023689235 hasConcept C192562407 @default.
- W2023689235 hasConcept C207114421 @default.
- W2023689235 hasConcept C2777240086 @default.
- W2023689235 hasConcept C2779070497 @default.
- W2023689235 hasConcept C2779200411 @default.
- W2023689235 hasConcept C2779444094 @default.
- W2023689235 hasConcept C2780377690 @default.
- W2023689235 hasConcept C2780378348 @default.
- W2023689235 hasConcept C33790079 @default.
- W2023689235 hasConcept C50515024 @default.
- W2023689235 hasConcept C71240020 @default.
- W2023689235 hasConcept C75473681 @default.
- W2023689235 hasConcept C8010536 @default.
- W2023689235 hasConceptScore W2023689235C120665830 @default.
- W2023689235 hasConceptScore W2023689235C121332964 @default.
- W2023689235 hasConceptScore W2023689235C126661725 @default.
- W2023689235 hasConceptScore W2023689235C135361552 @default.