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• W2023691105 abstract "A new enantioselective total synthesis of pachastrissamine (jaspine B) was achieved from a known α,β-unsaturated aldehyde by utilizing Córdova’s asymmetric epoxidation as the chirality-inducing step. The 2,3-cis stereochemistry of pachastrissamine was established via intramolecular epoxide ring opening of a γ,δ-epoxy-α,β-unsaturated ester intermediate coupled with oxy-Michael cyclization. Treatment of pachastrissamine with tetrahydro-2-furanol under acidic conditions led to smooth oxazolidine ring formation, furnishing jaspine A in a high yield." @default.
• W2023691105 created "2016-06-24" @default.
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• W2023691105 date "2010-01-23" @default.
• W2023691105 modified "2023-10-10" @default.
• W2023691105 title "Enantioselective Syntheses of Pachastrissamine and Jaspine A<i>via</i>Hydroxylactonization of a Chiral Epoxy Ester" @default.
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• W2023691105 doi "https://doi.org/10.1271/bbb.90670" @default.
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